8.1.07

etimología de la química orgánica

Los hidrocarburos son compuestos químicos compuestos por Carbono e Hidrógeno. Estos forman una cadena de carbonos. Son importantes por sus múltiples usos, como combustibles o disolventes, por ejemplo. Hay de muchos tipos, pueden ser cadenas lineales, o bien formar cadenas cerradas, incluso ambas cosas, o bien tener ramificaciones... Por ello son más difíciles de nombrar que otros compuestos más sencillos como son las sales inorgánicas. De hecho tienen su propia nomenclatura (es decir, técnicas empleadas para nombrarlas). Nomenclatura de compuestos orgánicos.

Una característica importante según las reglas de la IUPAC en su nomenclatura es el número de Carbonos que tiene (una segunda característica fundamental es la presencia de determinados grupos funcionales). En este post vamos a usar fundamentalmente los Alcanos, que son los que no tienen ningún grupo funcional y únicamente enlaces sencillos . Así si tienen 1 carbono usarán un prefijo distinto que si tiene 6.



Éste es el Hexano, que tiene 6 carbonos. Es un alcano porque todos sus enlaces son simples.



Para moléculas con más de 5 carbonos la cosa es fácil, ya que toman los prefijos griegos para los números. Así:
  • 5 Carbonos: Penta- (como por ejemplo pentano)
  • 6 Carbonos: Hexa- (como hexano)
  • 7 Carbonos: Hepta- (como Heptano)
  • 8 Carbonos: Octa- (como el Octano, ¿no os suena de la gasolina? )
  • 9 Carbonos: Nona-(como el Nonano)
...
y así sucesivamente.

Con los que tienen menos de 4 carbonos la cosa cambia, detrás de cada prefijo se esconde una pequeña historia.

Así, por ejemplo, con 4 carbonos, el prefijo usado es But (nuestro alcano sería el Butano, que es precisamente el gas que usamos en las cocinas y que, al menos en España, se vende en bombonas).
Pues bien, el origen de Butano proviene de la mantequilla. Y ¿qué tiene que ver la bombona de butano con la mantequilla? Muy sencillo. La raíz But- del Butano procede de ácido butírico, cuyo nombre fué acuñado por Eugene Chevreul (enlace en inglés) para designar a un ácido graso de la mantequilla . Mantequilla en latín se dice butyrum, de ahí el nombre . Por cierto, a este hombre le debemos más que la simpre relación entre la mantequilla y el naranja butanito, os recomiendo la lectura de su biografía.

Para los 3 carbonos usamos la raíz Prop- como en el Propano. El propano también se usa como combustible. Otra vez esta raíz procede de otro ácido orgánico, el ácido propiónico. El ácido propiónico fué sintetizado por Johann Gottilieb en 1844, pero su nombre se lo dió Jean-Baptiste Dumas (Dumas demostró que los riñones servían para eliminar urea e incluso fue ministro). Dumas observó que este ácido se comportaba como un ácido graso, si se añadía al agua no se mezclaba formando una película en su superficie. Pero este compuesto era muy pequeño para ser ácido graso (normalmente formado por muchos carbonos) así que lo llamó protopion (proto- primer, -pion: grasa) por ser el ácido graso más pequeño.

Para los 2 carbonos usamos la raíz Et- como en etano, o como etanol. El etanol (o alcohol etílico) es un viejo amigo del hombre, ya que es el componente fundamental de las bebidas alcohólicas. Esta raíz hay que buscarlo en Ethyl (inglés), que proviene del griego Ether+hyle (producto del éter). Sobre el orígen de esta raíz no he encontrado gran cosa (agradezco aportaciones). El éter era una sustancia empleada para explicar determinados fenómenos físicos, como la propagación de la luz en el vacío. Según esta teoría, el éter llenaba el espacio como un fluido. El experimento de experimento de Michelson-Morley puso fín a esta teoría sentando las bases de lo que sería la teoría de la relatividad. Pero es curioso que aún permanezcan restos de esa teoría en la nomenclatura química (tanto en esta raíz como en el éter)

Por último, para 1 Carbono, la raíz usada es Met-, como en Metano. El Metano es el hidrocarburo más sencillo. Está presente en el gas natural y es el principal componente del biogas. También es un muy importante gas de efecto invernadero, siendo sus principales fuentes los pantanos y las vacas (concretamente sus ventosidades). Dentro de este grupo también nos encontramos con el Metanol o alcohol metílico. El Metanol es un componente minoritario del vino, es muy tóxico, y es responsable de la resaca. Este producto se lleva usando desde época de los egipcios, que lo empleaban para el embalsamiento. Los primeros en describir el metanol fueron Jean-Baptiste Dumas otra vez y Eugene Peligot, y le pusieron el nombre de "metileno" que significa producto de árboles (meth + hyle) , ya que se destila de la madera. De ahí salió la raíz met-.

Ruego que disculpen posibles equivocaciones y ambigüedades. Prometo ir corrigiéndolo y mejorando.

El Gato Cuántico

Corrección: el metanol no es el responsable de las resacas, pero sí de otras cosas peores, ya que es muy tóxico (ver comentarios)

Referencias:
la siempre útil Wikipedia
Lenguaje, ciencia e historia: una introducción histórica a la terminología química. Antonio García Belmar y Jose Ramón Bertolomeu Sánchez

con la colaboración de Chemist


179 comentarios:

Azuara dijo...

Aunque sólo has hablado de los alcanos, sus ácidos derivados también tienen nombres curiosos; véase el etanoico y el metanoico, del vinagre y la hormiga , respectivamente ;)

chemist dijo...

azuara los nombres etanoico y metanoico proceden de las raíces que ha explicado Gato. Sus otros nombres (acético y fórmico) son los que proceden de vinagre y hormiga. Perdona si querías decir eso es que no me ha quedado nada claro.
Un pequeño apunto Gato, la resaca no procede del metanol (muy perseguido y casi ausente en el alcohol ya que produce ceguera y finalmente la muerte). La resaca la produce el acetaldehído que se produce en la ruta metabólica del etanol (Etanol => acetaldehído => acético => meadilla). Como curiosidad en Japón hay una deficiencia genética endémica, el acetaldehído no es convertido eficazmente por el cuerpo en acético (por un defecto de la acetaldehidodeshidrogenasa) por lo que los japoneses casi sin beber se abutargan.

el gato cuantico dijo...

gracias a ambos por los comentarios.

tenía reservados otros nombres para futuras entregas, entre ellas el acético y el fórmico.

y ya he corregido el error del metanol

Azuara dijo...

Me refería a eso chemist :)

ilrahtala dijo...

Esto que os cuento a proposito del etanol no lo he conseguido verificar... pero ahi va:
Como bien sabéis a las bebidas alcoholicas se las llama "espirituosas" y una vez escuche que los gases resultantes del proceso de destilacion se pensaba que eran espiritus. la etimologia del termino vendria de algo similar a "spirit drink" y de ahi la traduccion a bebidas espirituosas que ya sabemos que alegran el espiritu.. Aunque la cosa parece que no iba por ahi.
No tengo ni idea de cuanto hay de verdad en todo esto que he dicho (bueno sí que estoy seguro de que los primeros que fabricaron bebidas alcoholicas no sabian lo que era un gas como hoy lo conocemos ^^ pero la historia es, cuanto menos, curiosa.

Anónimo dijo...

hola, ademas de darte las gracias por publicar esta util informacion encontre algo sobre la etimologia del eter aunque algo tecnico es esto y espero que te sirva Del lat. aether, y este del gr. αἰθήρ

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